Titrators are used to determine the concentration of a specified analyte, using a common method of quantitative chemical analysis known as titration. The characterization of a custombuilt coulometric karl fischer titration apparatus article in journal of chemical education 879 july 2010 with 83 reads how we measure reads. This titrator was designed in germany as part of the hach titralab family of automatic titrators and allows you to quickly measure moisture content. The data capture software is an easy to use and flexible solution to collect measurement results from different kem instruments refractometers, density meters, potentiometric or karlfischer titrators, thermal conductivity meters on a windows personal computer. K90500 automatic potentiometric titrator, 115v, 60hz k90590 automatic potentiometric titrator, 230v, 50hz accessories k905001 karl fischer titrator burette assembly k905002 filter desiccant dryer tube k905003 magnetic stirrer with holding ring k905004 magnetic stirrer with electrode arm k905005 vessel heating cooling accessory. The instructions in this document refer to titrators running firmware version 5.
Titrators we offer a variety of titrator products to meet your needs. Karl fischer titrator for volumetric water content. Internal external you can attach the mettler toledo dv705 kf titration stand as an external titration stand. It was invented in 1935 by the german chemist karl fischer. With it, water contents from a few ppm to 100% can be determined reliably and precisely in solid, liquid and gaseous samples. When the over titration period causes a noticeable change in color, does this mean i should discard the karl fischer.
Get your karl fischer titration system on the way by clicking add to cart today. Scientific aquamax kf coulometric karl fischer titrator. Karl fischer titration calculation chromatography forum. Kfwin software enables your pc to control kems kf moisture titrators including mkc710b, mkv710b, mkc520, mka520, mks520, mkc510n, mka510n and mks510n. Measurement results are convert ed to pdf and can be stored in a usb flash drive. The operating voltage is indicated on the specification plate. This hydranal manual is intended to be a useful reference handbook for analysts performing routine karl fischer. Potentiometric titrators karl fischer titrators hiranuma automatic titrator com1700a series automatic titrators designed to meet your needs now and in the future. The easy way to transfer your results directly to microsoft excel. Kf or kft it remains the primary method of water content determination used worldwide by.
Nonobservance of this provision may result in damage to the titroline. Coulometric kf titration iodine electrochemically generated from the oxidation of iodide contained in the coulometric kf reagent calculation based on the amount of produced consumed current over time acc. Same manual titration and dosing function as the piston burette titronic. Volumetric karl fischer titration is suit able for samples with a water content in the range 100 ppm to 100 %. Depending on your application, critical components can become worn or decayed which may cause a. View and download mettler toledo dl32 operating instructions manual online. The focus has been consciously put on linking application information with our lab findings and making this accessible to you in a practical. Applying usp to your moisture determination lab and.
These instruments utilize preset application packs to deliver accurate and reliable results straight from the box, allowing anyone in the laboratory to. The volumetric karl fischer titration is concerned with the water determination from 15 % up to 100% content in the most different samples such as in foods, polymers and plastics. The karl fischer titration is merely a means of measuring sample water content. The instrument has a grip for handheld operation or it can be clamped to a titrastir stir plate or laboratory stand for stationary setups. About karl fischer titration kft agnieszka kossakowska honeywell research chemicals and michael margreth metrohm are kft experts who share their knowledge and experience with users of this technique at seminars across the globe. The amount of current required to convert the water is the determinant of the amount of moisture. The inexpensive 870 kf titrino plus is a kf titrator for volumetric water content determination. Karl fischer titrator, volumetric karl fischer titrators, ma. Complete solutions for the volumetric and coulometric water content determination with karl fischer titration. Via usb slave port, usbrs232 converter optional generation of forgeproof pdf reports without a pc yes usb flash drive for saving methods, results and pdf reports yes ethernet interface to connect to a local network for data archiving or printing on network printers yes temperature sensor pt or ntc. The basics of karl fischer titration karl fischer titration is an analytical technique to measure the amount of water contained in various samples, which may be solid, liquid or gaseous.
Combining coulometry with the karl fischer method, aquamax kf titrators determine the water content of samples by measuring the amount of electrolysis current necessary to produce the required iodine this is an absolute technique which does not require the calibration of. We offer a variety of titrator products to meet your needs. As opposed to other methods, such as drying ovens or infrared lamps, karl fischer titrators determine the actual water content in a sample, whereas other methods determine all volatile components that evaporate under the influence of heat. Easyplus titration easy ph easy ox easy cl easy pro.
Karl fischer titrators advanced digital automatic karl. Karl fischer titrator for volumetric water content determination. Karl fischer titrator manufacturer,karl fischer titrator. For a comprehensive description of the instrument and its functions, refer to the operating instructions, supplied as. They can immediately be used by the instrument without. Export the results as pdf or csv, also to networks.
Electrode cable for plug in head uplug f, 2x2 mm b, 1m. Certain samples such as polymers require the use of kf oven in which the sample is heated and moisture in vapour form is taken to the titration vessel with a carrier gas. Operating instructions mettler toledo dl37 kf coulometer. Aquastar reagents for volumetric karl fischer titration. The optimum recording range is 10mg of water per sample. The end point of the titration is recorded using bivoltametric indication. Builtin tutorial, online context help, and learn titration modes help. Gr scientific, 70, aquamax coulometric karl fischer titrator.
The characterization of a custombuilt coulometric karl. Kinetically controlled doses of karl fischer reagents are added to the solution in a hermetically sealed vessel as per stop criteria selected and the end point. Repeat the same procedure by resetting the instrument to obtain 3 values for the factor of kf reagent which is not differing by 0. Safe handling of reagents, easier titration through automatic titration start. Up to 4 titrators, at710b potentiometric titrators, mkv710b volumetric or mkh7102nd hybrid or additional mkc710b coulometric karl fischer moisture titrators can be connected and simultaneous measurement is possible. It enables you to manage titration results in a common electronic file and to show results on any pc without installation of additional software. Operation lock you can lock the kfwin when you leave the titrator during titration.
Additionally, with the 900 touch control, 915 kf titouch and 916 titouch you can send a pclims report directly via ethernet to tibase. Agc book 20% cyanbasics of titration titration theory basics of titration. Most applications are served by the four preprogrammed titration programs, though individual programs are also possible. Water determination by karl fischer titration request pdf. I understand acidbase titration calculations but need some help with kf titration because im not sure how to convert mg of kf reagent into mole of kf reagent. Omnis volumetric karl fischer titrator for water content and moisture. Request pdf water determination by karl fischer titration a variety of analytical techniques have been used for water determination. Aq300 karl fischer coulometric titrator karl fischer. Using kf titrators to determine water content posted on october 22, 2018 december 19, 2018 by marcelo luftman the karl fisher titration method was published to determine trace amount of water samples in nonaqueous systems that contained sulfur dioxide. Tests water in the range from 100 ppm to 100% simple and automatic titrant. Free pdf converter is 100% adobe compatible tool converting various types of files like word, excel, postscript, powerpoint, richtext and others to pdf. For optimal execution of the kf titration, the ph of the solution should be in the range between 4 and 8. History of karl fischer titration the milestones 1980 changed the world of kf titration 8 1935 karl fischer published a reagent for water determination consisting of iodine, so2, pyridine and methanol 1979 eugen scholz and helga hoffmann, riedelde haen, replaced pyridine by imidazole and invented hydranal reagents. Kfwin is designed to control the moisture titrator unit including start and reset of it, and set conditions and parameters of titration or sample materials from the pc.
Electrode cable for plug in head uplug f, 2x2 mm b, 1m order number. A coulometric karl fischer instrument is often referred to as a. Automated titrator is an essential analytical instrument for quality control and chemical analysis. Start guide for use in the lab and paper and pdf manuals. Both new titrators are characterized by the following. With the mettler dl37 kf coulometer you can easily determine traces of water with a very high degree of accuracy. Titralab is suitable for all kf solvents and reagents, whereby both one and twocomponent reagents can be used. Automatic titrator, automatic potentiometric titrators. Pdf the coulometric karl fischer titration is concerned with the. View and download metrohm 870 kf titrino plus manual online. Product description aquamax kf plus titrators have been specifically designed for the determination of water content. Where substances react with methanol, karl fischer titration is carried.
Measuring priciple of karl fischer moisture titrators. Sop for calibration of karl fischer apparatus standard operating procedure to calibrate the karl fischer apparatus with disodium tartrate. Our most intelligent and advanced titrator ever produced, the com1700a series. Volumetric karl fischer titration is recommended for determining water contents in samples with water levels of between 0. Automatic potentiometic and karl fischer volumetric titration. Today, the titration is done with an automated karl fischer titrator. This video shows how to determine the titrant concentration using a syringe, a precision balance connected to the mettler toledo volumetric karl fischer titrator. Kf the water determination test karl fischer method is designed to determine water content in substances, utilizing the quantitative reaction of water with iodine and sulfur dioxide in the presence of a lower alcohol such as methanol and an organic base such as pyridine, as shown in the following formula. Karl fischer titrators for water moisture determination metrohm. Karl fischer titration is a method for moisture determination that is specific to water. About this document this document provides you with the information you need to get started with your mettler toledo titrator. Easyplus titrator 2 push the blue release button to install the titration head on stirrer rod. The aquamax kf titrator is located underneath the glassware case or inside the optional carry case if ordered. These two types are volumetric and coulometric titrators, and their gen eral features include.
The coulometric kf titrator is an easytooperate instrument for coulometric karl fischer titrations. Pdf output various data including results and methods can be output in pdf format. Titrator service while your mettler toledo titrator is known for its accuracy and dependability, proper care is required to keep it performing at its peak potential. The compact volumetric karl fischer titrators have been designed for a wide range of water content applications. Two types of karl fischer titration volumetric iodine is added mechanically to a solvent containing the sample water is quantified from the volume of kf reagent consumed 100 to 1x106 ppm 0. The aquamax kf provides an industry leading solution for companies interested in coulometric karl fischer titration analysis. Exporter of karl fischer titrators advanced digital automatic karl fischer moisture analyzer, digital automatic karl fischer titrator, veegomaticiii karl fischer titrators and digital automatic titration apparatus offered by veego instrument corporation, mumbai, maharashtra. Spectralab volumetric karl fischer titrator has been designed for a wide range of water content application ranging from 10 ppm to 100% of moisture by volumetric method. Volumetric kf titrator v10sv20sv30s user manual 30297193c 7182017 12. Our titrator product offering includes electronic burettes, products for acidbase titrations, units with endpoint and equivalence point titration, meters for redox titrations, and products for karl fischer volumetric around 1% and coulometric at lower levels titrations. With its user interface, which is tailored to routine users, the 870 kf titrino plus is so simple to operate that only brief orientation periods are required. There are two types of titrators generally used for this purpose. Its efficient, userfriendly design and portability make the aquamax kf unique from other such titration analysis instruments. Karl fischer titration is the method of choice for water content determination.
Our titrator product offering includes electronic burettes, products for acidbase titrations, units with endpoint and equivalence point titration, meters for redox titrations, and products for karl fischer volumetric around 1% and coulometric at. Coulometric titration is mainly employed for low water content determination according to the karl fischer titration technique. The kf is an accurate, reliable and easy to use instrument for performing volumetric titrations in the laboratory. The microprocessor with high performance controls automatically all electrolysis adjustments. Determine titrant concentration karl fischer titrator. Measurement results are convert ed to pdf and can be stored in a. Karl fischer titration is simply a means to measure water content of samples. Titer and reagent calibration determination of water content using volumetric karl fischer titration is based on the stoichiometric reaction between the components of the reagent and moisture contained in the sample. Kf volumetric titrator for karl fischer titrations hach usa. Titrations with electrochemical reagent generation simple by one click in the userfriendly software.
The denver model 260 titration controlleris a powerful, versatile and accurate instrument offering many advanced options, programmable standardization, quick update rates of twice per second for all channels. Karlfischer titration the method for determining water. Applied technical services performs karl fischer testing to determine the moisture content of sample materials. Using advanced control technology, this titrator gives the highest accuracy and precision in a minimum amount of time. The coulometric karl fischer titrator titroline kf trace is the dedicated instrument for determining even smallest water content in your samples. Titrator or in personal injury or damage to property.
With the dl37 you have the possibility to adapt the titration parameters control gain, end point indication, etc. This method was originally developed in the 1930s by german chemist karl fischer. Moisture can affect product quality, texture, shelf life, chemical stability and reactivity, and the karl fischer volumetric titration is a universally acknowledged method used in all types of. Hoffmann investigated ways to improve karl fischer titration, making it safer. The coulometric karl fischer titration is concerned with the determination of traces of water from e. Specific features for the titroline 7500 kf polarizable electrode input for set endpoint titrations dead stop. The instrument covers a measuring range from 100 ppm to 100% water. Prior to switching the device on it has to be ensured that the operating voltage of titroline.
Coulometric kf titrator manufacturer, exporter, supplier. For an electrochemically optimized karl fischer cell, the current conversion efficiency for. As kf8 is not compatible with ipad, nook, kobo devices, so we need a kf8 converter named ultimate ebook converter epubor ultimate to help us convert kf8 to pdf. Karl fischer titration 37 volumetric kf titrators volumetric kf titrators overview 870 kf titrino plus 915 titouch 890 titrando 901 titrando titration to preset phmv endpoints set yes ph calibration and ph measurements cal, meas yes realtime curve display yes yes yes yes yes yes yes yes. The v20 is the ideal karl fischer volumetric titrator designed for a wide range of applications to determine water content in liquids and solids. Karl fischer titration is a classic titration method in analytical chemistry that uses coulometric or volumetric titration to determine trace amounts of water in a sample. Karl fischer moisture titrator volumetric titration karl fischer moisture titrator coulometric titration option mkv710m mkc710m cn073a 1811 pdf kt benttype sampler for powder 1204576 mkv. It is possible that iodine diffuses to the cathode and convert to iodide ions. Kf volumetric titrator for karl fischer titrations hach. History of karl fischer titration karl fischer march 24, 1901 april 16, 1958 was a german chemist published a method in 1935 to determine trace amounts of water in samples.
Each digital titrator comes with five delivery tubes and a methods manual, which covers the most commonly tested parameters and the corresponding titrant cartridges. You can check the performance of your titrator by periodically running water standards such as those supplied with coulo formula reagents. This kf instrument can be expanded for automated titration. The at and kf instruments are one touch, automatic laboratory analyzers covering both potentiometric titration at series and karl fischer volumetric titration kf series. The volumetric kf titrator is an easytooperate instrument for volumetric karl fischer titrations. At the end of the titration, the display will show the result in mg of h2o 5 ml of kf reagent. Kf volumetric titrator for karl fischer titrations. Water is determined by method i subheading a, unless noted in the individual monographs.
Modern instruments, such as the aquamax kf, apply the coulometric principle, whereby the water present in the sample is coulometrically titrated to a predefined endpoint at which free iodine exceeds a minute. Mettler toledo titrators offer a broad range of possibilities to handle your data. Pdf coulometric karl fischer titration researchgate. Karl fischer moisture titrator coulometric titration kem kyoto. The karl fischer titration is based on an iodine iodid reaction. The easy kfv titrates for water content in a wide variety of samples from any industry. Modern instruments, such as the aquamax kf, use the coulometric principle, whereby the water present in the sample is coulometrically titrated to a predefined end point at which there is a minute excess of free iodine present. Table of contents 8 handling and maintenance quality management and validation with metrohm 65 9 troubleshooting karl fischer titration 66 miscellaneous. Thank you for choosing a mettler toledo coulometric kf titrator.
No matter where the technical training is performed, they often encounter the same questions. Application news, practical tips for the laboratory, and more. Karl fischer kf titration the method i has 3 sub headings a, b, c as listed to the right. Mettler toledo good titration practicetm in kf titration. Although in principle standardisation of a coulometer is not necessary since the water titrated is a direct function of the coulombs of electricity consumed, the astm methods for measuring water content of crude oil and petroleum products stipulate. This video describes how to calibrate an oil or water titrator test kit for laboratory use. The pocket titrator kf is a truly portable and easy to use coulometric titrator. Method i a direct titration test specimen is added to the titrator and moisture is directly titrated. The amounts of water generally determined via coulometric karl fischer. Karl fischer titration, karl fischer method, coulometric, volumetric. Smallpdf the platform that makes it super easy to convert and edit all your pdf files. The karl fischer titration is a titration method for measuring water content in basically all types of substances. With the new generation of mettler toledo compact volumetric and coulometric karl fischer titrators v20v30, c20c30 and excellence combined general and volumetric kf titrators t70 and t90, water determination has reached an unrivaled level of simplicity and security. Karl fischer determination is the benchmark for water content analysis.
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